Kinetics of depletion interactions

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Kinetics of depletion interactions

– Depletion interactions between colloidal particles dispersed in a fluid medium are effective interactions induced by the presence of other types of colloid. They are not instantaneous but build up in time. We show by means Brownian dynamics simulations that the fluctuations in the depletion force between two guest particles in a host dispersion of differently sized colloids do not decay expon...

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We consider the interactions between two uncharged planar macroscopic surfaces, immersed in an electrolyte solution, which are induced by interfacial selectivity. These forces are taken into account by introducing a depletion free-energy density functional, in addition to the usual mean-field Poisson-Boltzmann functional. The minimization of the total free-energy functional yields the density p...

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Depletion interactions in colloid-polymer mixtures.

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Repulsive depletion interactions in colloid–polymer mixtures

Depletion forces in colloidal systems are known to be entirely attractive, as long as the background of macromolecules is small enough that an ideal gas approach is valid. At higher densities, however, structural correlation effects of the macromolecules which lead to additional repulsive parts in the depletion interaction, have to be taken into account. We have measured the depletion interacti...

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ژورنال

عنوان ژورنال: Europhysics Letters (EPL)

سال: 2003

ISSN: 0295-5075,1286-4854

DOI: 10.1209/epl/i2003-00393-0